| March | July | P value | ||||
---|---|---|---|---|---|---|---|
Mean ± SD | Median | Min–max | Mean ± SD | Median | Min–max | ||
Mass concentration (μg/m 3 ) | |||||||
PM2.5 | 60.29 ± 15.48 | 58.71 | 40.74–81.49 | 9.72 ± 2.59 | 10.52 | 6.57–12.71 | <0.0005 |
Carbon (μgC/m 3 ) | |||||||
Organic | 21.47 ± 7.00 | 18.78 | 13.51–31.93 | 2.22 ± 0.95 | 2.63 | 080–3.29 | <0.005 |
Elemental | 7.72 ± 1.68 | 7.39 | 5.80–10.77 | 1.52 ± 0.57 | 1.61 | 0.75–2.15 | <0.0005 |
Total | 29.19 ± 8.58 | 26.18 | 19.36–42.70 | 3.73 ± 1.50 | 4.22 | 1.54–5.19 | <0.001 |
Ion (μg/m 3 ) | |||||||
Cl− | 0.710 ± 0.22 | 0.646 | 0.556–1.176 | 0.0302 ± 0.0197 | 0.0254 | 0.0106–0.0716 | <0.001 |
NO3 − | 2.60 ± 0.86 | 2.77 | 1.49–3.47 | 0.0496 ± 0.0477 | 0.0471 | N.D.–0.1169 | <0.001 |
SO4 2− | 3.83 ± 0.98 | 4.37 | 2.26–4.58 | 0.5260.156 | 0.522 | 0.764 | <0.0005 |
Na+ | 0.0846 ± 0.0194 | 0.0846 | 0.0604–0.1084 | 0.0183 ± 0.0100 | 0.0174 | 0.0085–0.0390 | <0.0005 |
NH4 + | 2.80 ± 0.65 | 3.04 | 1.71–3.42 | 0.206 ± 0.072 | 0.194 | 0.115–0.317 | <0.0005 |
K+ | 0.0242 ± 0.0250 | 0.0138 | 0.0024–0.0637 | 0.000681 ± 0.001370 | N.D. | N.D.–0.003639 | N.S. |
Mg2+ | N.D. | N.D. | N.D. | N.D. | N.D. | N.D. | – |
Ca2+ | 0.290 ± 0.064 | 0.265 | 0.227–0.371 | 0.262 ± 0.098 | 0.284 | 0.111–0.407 | N.S. |
Metal (ng/m 3 ) | |||||||
Na | 111.75 ± 39.91 | 100.84 | 65.86–165.06 | 67.57 ± 109.06 | 28.03 | 16.03–314.64 | N.S. |
Al | 113.10 ± 68.34 | 115.55 | 34.11–204.03 | 62.65 ± 90.09 | 21.68 | N.D.–234.25 | N.S. |
Si | 108.74 ± 47.95 | 111.34 | 46.51–163.46 | 89.81 ± 84.82 | 56.57 | 20.96–266.00 | N.S. |
K | 116.17 ± 35.86 | 101.89 | 74.88–172.71 | 112.97 ± 154.26 | 51.86 | 41.74–461.23 | N.S. |
Ca | 315.09 ± 149.22 | 265.58 | 193.68–559.36 | 192.02 ± 106.51 | 172.92 | 80.57–392.83 | N.S. |
Sc | 0.0184 ± 0.0076 | 0.0203 | 0.0050–0.0257 | 0.0104 ± 0.0079 | 0.0079 | 0.0026–0.0245 | N.S. |
Ti | 6.16 ± 2.60 | 4.95 | 3.69–10.14 | 4.93 ± 2.77 | 3.42 | 3.20–10.16 | N.S. |
V | 0.482 ± 0.134 | 0.485 | 0.267–0.637 | 0.174 ± 0.110 | 0.137 | 0.061–0.402 | <0.005 |
Cr | 14.36 ± 10.81 | 12.777 | N.D.–28.059 | 0.772 ± 1.787 | N.D. | N.D.–4.793 | <0.05 |
Mn | 4.80 ± 1.05 | 4.96 | 3.48–6.20 | 4.28 ± 1.81 | 3.74 | 2.29–7.58 | N.S. |
Fe | 217.82 ± 114.46 | 276.11 | 67.41–322.63 | 86.65 ± 43.46 | 87.67 | 34.73–167.96 | <0.05 |
Co | 0.115 ± 0.034 | 0.112 | 0.060–0.157 | 0.0455 ± 0.0265 | 0.0339 | 0.0285–0.1029 | <0.005 |
Ni | 0.469 ± 0.203 | 0.448 | 0.154–0.778 | 0.110 ± 0.049 | 0.096 | 0.056–0.184 | <0.01 |
Cu | 4.68 ± 2.68 | 3.82 | 2.51–9.69 | 1.73 ± 0.46 | 1.52 | 1.08–2.33 | <0.05 |
Zn | 53.02 ± 27.04 | 51.33 | 27.64–101.61 | 18.14 ± 17.19 | 12.25 | 2.82–49.45 | <0.05 |
As | 14.14 ± 4.77 | 13.97 | 8.39–22.61 | 0.409 ± 0.267 | 0.33 | 0.21–0.99 | <0.001 |
Se | 0.233 ± 0.092 | 0.234 | 0.106–0.349 | 0.0724 ± 0.0386 | 0.0562 | 0.0384–0.1441 | <0.01 |
Rb | 0.338 ± 0.068 | 0.330 | 0.265–0.425 | 0.162 ± 0.062 | 0.138 | 0.114–0.286 | <0.001 |
Mo | 0.133 ± 0.071 | 0.131 | 0.033–0.227 | 0.0352 ± 0.0319 | 0.0225 | 0.0133–0.1031 | <0.05 |
Sb | 0.988 ± 0.422 | 1.065 | 0.412–1.414 | 0.466 ± 0.277 | 0.621 | 0.114–0.800 | <0.05 |
Cs | 0.0816 ± 0.0276 | 0.0771 | 0.0511–0.1308 | 0.0197 ± 0.0108 | 0.0145 | 0.0120–0.0388 | <0.005 |
Ba | 29.84 ± 39.18 | 6.74 | 3.44–95.01 | 3.31 ± 2.74 | 2.15 | 1.82–9.43 | N.S. |
La | 0.0955 ± 0.0383 | 0.0795 | 0.0626–0.1445 | 0.198 ± 0.171 | 0.150 | 0.050–0.512 | N.S. |
Ce | 0.197 ± 0.077 | 0.169 | 0.128–0.291 | 0.143 ± 0.076 | 0.109 | 0.072–0.288 | N.S. |
Sm | 0.0163 ± 0.0077 | 0.0127 | 0.0099–0.0261 | 0.0110 ± 0.0073 | 0.0077 | 0.0059–0.0255 | N.S. |
Hf | 0.00293 ± 0.00170 | 0.00266 | 0.00090–0.00588 | 0.00151 ± 0.00079 | 0.00116 | 0.00066–0.00301 | N.S. |
Ta | 0.000345 ± 0.000387 | 0.000290 | N.D.–0.001039 | 0.000040 ± 0.000105 | N.D. | N.D.–0.000278 | N.S. |
W | 0.211 ± 0.169 | 0.141 | 0.034–0.462 | 0.0220 ± 0.0299 | 0.0076 | 0.0070–0.0883 | <0.05 |
Pb | 12.34 ± 5.73 | 10.41 | 8.29–23.56 | 12.27 ± 11.42 | 6.92 | 2.67–34.15 | N.S. |
Th | 0.0232 ± 0.0152 | 0.0174 | 0.0083–0.0459 | 0.00964 ± 0.00633 | 0.00675 | 0.00522–0.02305 | N.S. |