Table 3 Calculated rate constants for the gas phase decomposition of Zn[(C6H5)PSSe]2 at 800K
Reaction pathway | kuni (s−1) | Keq | krec (s−1) |
|---|---|---|---|
INT4/s → P1/s | 1.76 × 10−13 | 2.83 × 10−4 | 4.97 × 10−17 |
INT4/s → P2/s | 7.75 × 10−13 | 5.82 × 10−8 | 4.51 × 10−20 |
INT5/s → P3/s | 1.44 × 10−11 | 1.45 × 102 | 2.10 × 10−9 |
INT5/s → P4/s | 3.05 × 10−9 | 8.19 × 101 | 2.50 × 10−7 |
INT6/d → P5/s | 9.34 × 10−3 | 1.45 × 107 | 1.36 × 105 |
INT6/d → P6/s | 5.61 × 10−4 | 8.33 × 101 | 4.67 × 10−2 |
INT6/d → P7/s | 3.20 × 10−1 | 1.08 × 1015 | 3.47 × 1014 |
INT7/s → P8/s | 5.87 × 10−8 | 1.41 × 10−6 | 8.30 × 10−14 |
INT7/s → P9/s | 1.98 × 10−7 | 4.58 × 10−10 | 9.05 × 10−17 |
INT7/s → P10/s | 1.52 × 10−3 | 1.21 × 10−1 | 1.84 × 10−4 |