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Table 5 Calculated rate constants and half-lifes for the disappearance of caffeine in water at 30°C, extrapolated from experimental data

From: Caffeine in surface and wastewaters in Barbados, West Indies

pH

k (min −1 )

Half-life (Years)

6

6.6×10−11

2.0×104

7

6.6×10−10

2.0×103

8

6.6×10−9

2.0×102

9

6.6×10−8

2.0×101