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Table 1 Target compound and internal standards GC-MS and analytical parameters; chemical formulas, the chromatographic retention times, the mass spectrometric multiple reaction monitoring (MRM) ion transitions, external standard calibration linearity, the limits of detection (LOD) and quantification (LOQ) and percentage recovery of the analyte

From: Caffeine in surface and wastewaters in Barbados, West Indies

Compound

Chemical formula

Retention time (min)

MRM transition

Linearity (R 2 ) a

LOD (ng L −1 )

LOQ (ng L −1 )

Recovery (%)

Caffeine

C8H10N4O2

8.4

194 109

0.999(7)

0.2

1.0

95 - 100

Dichlorobenzene

C6H4Cl2

4.2

146 111

-

-

-

-

13C3 Caffeine

C8H10N4O2

8.4

197 111

-

-

-

-

  1. aNumber of points used for linear regression is in parenthesis.
  2. aLinear range 0.1 - 50 μg L−1.