Table 1 Summary of LIB anode materials (non-carbon) containing graphene

SnO₂/graphene

orthorhombic

Hydrothermal

First discharge capacity 1588 mAhg^-1, after 40 cycles remain 730 mAh/g

(Zhu et al.2011)

Si/graphene

Cubic diamond type

Hydrazine reduction

First discharge capacity 2753 mAhg^-1, after 50 cycles remain 590 mAh/g

(Liu et al.2012; Wang et al.2010a)

Co₃O₄/graphene

spinel

Solvothermal

First discharge capacity 1826 mAhg^-1, after 40 cycles maintain 1310 mAh/g

(Lian et al.2010a)

Mn₃O₄/graphene

spinel

Hydrothermal

First discharge capacity 900 mAhg^-1, after 100 cycles maintain 390 mAh/g

(Tao et al.2012)

CuO/graphene

sphalerite

N-methyl-2-p yrrolidone solvent

First discharge capacity 640 mAhg^-1, after 50 cycles maintain 583.5 mAh/g.

(Wang et al.2010b)

Fe₃O₄/graphene

Trans spinel

Reduction

First discharge capacity 1426 mAhg^-1, after 100 cycles maintain 580 mAh/g

(Kim et al.2012)

TiO₂/graphene

Rutile type

Gas/liquid interface reaction

First discharge capacity 499 mAhg^-1, after 10 cycles maintain 150 mAh/g

(Tung et al.2009)

CeO₂/graphene

Face-centered cubic

Hydrothermal

First discharge capacity 1469 mAhg^-1, after 100 cycles maintain 605 mAh/g

(Cai et al.2012a)

SnS₂/graphene

Hexagonal crystal structure

Solution phase method

First discharge capacity 1664 mAhg^-1, after 500 cycles maintain 600 mAh/g

(Wang et al.2011a)

Fe₃O₄-SnO₂-gra-phene

——————

Gas–liquid interfacial reaction

First discharge capacity 1740 mAhg^-1, after 115 cycles maintain 1198 mAh/g

(Chang et al.2012)

Li₄Ti₅O₁₂/graphe-ne

Spinel

Sol–gel method

First discharge capacity 430 mAhg^-1, after 35cycles maintain 150 mAh/g

(Lian et al.2011; Choucair et al.2009a)