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Table 1 Various evaluated components for the determination of mercury in SPM samples

From: Quantifying uncertainty in measurement of mercury in suspended particulate matter by cold vapor technique using atomic absorption spectrometry with hydride generator

Sample I.D.

SPM (μg/m3)

Concentration of mercury obtained from AAS-HG after reducing blank (μg/litre) [CHg]

Volume made for test samples (mL) [V TEST ]

Total weight of SPM deposited on 18 cm × 23 cm filter paper (g) [W TSPM ]

Weight of SPM deposited on 18 cm × 11.5 cm filter paper area taken for analysis (g) [W ANA ]

Volume of air processed through HVS at STP, (m3) [V HVS ]

Recovery of the analytical procedure (%) [R HVS]

**Concentration of mercury in ng/m3C(MHg)

S-1

395

58.22 (2.82)*

50

0.17744

0.08872

493.52

94.39

12.55 ± 2.44

S-2

203

23.41 (2.13)*

50

0.09124

0.04562

414.97

6.00 ± 1.23

S-3

2337

62.32 (4.13)*

50

1.05086

0.52543

457.16

14.50 ± 2.87

S-4

251

6.83 (1.12)*

50

0.11279

0.05639

456.66

1.59 ± 0.37

S-5

338

14.04 (0.92)*

50

0.15214

0.07607

471.24

3.17 ± 0.63

S-6

429

23.11 (1.62)*

50

0.19300

0.09650

417.58

5.89 ± 1.17

S-7

347

16.6 (1.33)*

50

0.62306

0.31153

391.63

 

4.51 ± 0.91

  1. *Value in parentheses is the standard deviation of six determinations of two replicates (three each).
  2. **Concentration of metal mercury has been calculated by using eq.-1 and values reported with expanded uncertainty in ng/m3.