From: Syntheses, characterizations and thermal analyses of four novel unsymmetrical β-diketiminates
Bond length (Å) | 4a | 4b | 4c | 4d |
---|---|---|---|---|
N(1)-C(2) | 1.3269(16) | 1.3476(15) | 1.3530(13) | 1.3293(15) |
N(1)-C(6) | 1.4151(15) | 1.4220(15) | 1.4222(12) | 1.4148(15) |
N(2)-C(4) | 1.3231(15) | 1.2965(14) | 1.3036(13) | 1.3154(14) |
N(2)-C(12) | 1.4270(14) | 1.4268(13) | ||
N(2)-C(13) | 1.4240(13) | 1.4234(12) | ||
C(1)-C(2) | 1.5065(18) | 1.5015(16) | 1.5039(14) | 1.5059(15) |
C(2)-C(3) | 1.4001(17) | 1.3680(16) | 1.3777(14) | 1.3897(16) |
C(3)-C(4) | 1.3987(17) | 1.4352(16) | 1.4382(13) | 1.4091(15) |
C(4)-C(5) | 1.5065(16) | 1.551(6) | 1.5144(13) | 1.561(3) |
C(9)-C(12) | 1.5093(18) | |||
O(1)-C(9) | 1.3706(12) | |||
O(1)-C(12) | 1.4283(15) | |||
Cl(1)-C(9) | 1.7408(12) | |||
Bond angles (°) | 4a | 4b | 4c | 4d |
C(2)-N(1)-C(6) | 124.56(11) | 126.93(10) | 127.61(9) | 124.80(10) |
C(4)-N(2)-C(12) | 123.06(10) | 122.54(9) | ||
N(1)-C(2)-C(3) | 120.69(11) | 120.78(10) | 120.80(9) | 120.59(10) |
N(1)-C(2)-C(1) | 121.36(12) | 119.51(11) | 119.58(9) | 121.22(11) |
C(3)-C(2)-C(1) | 117.90(12) | 119.69(11) | 119.62(9) | 118.17(10) |
C(4)-C(3)-C(2) | 126.12(11) | 126.13(10) | 125.84(9) | 125.85(10) |
N(2)-C(4)-C(3) | 121.25(11) | 121.18(10) | 120.77(9) | 121.65(10) |
N(2)-C(4)-C(5) | 120.14(11) | 122.6(2) | 122.63(9) | 119.30(13) |
C(3)-C(4)-C(5) | 118.61(11) | 114.4(2) | 116.60(8) | 116.53(13) |
C(4)-N(2)-C(13) | 120.72(9) | 120.70(8) | ||
C(9)-O(1)-C(12) | 116.54(9) |