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Table 2 Effect of varying p-toluenesulfonamide (TsNH 2 or PTS) on the rate of reaction at 300 K a

From: Oxidation of tricyclic antidepressant drugs with chloramine-T in acidic solutions: kinetic, mechanistic and thermodynamic studies

103[PTS]

104 k /(s-1)

(mol dm-3)

[IMP]

[CLM]

2.0

7.24

4.03

4.0

5.24

3.42

5.0

4.79

2.86

8.0

3.98

1.94

  1. a[CAT]o = 2.0 x 10-4 mol dm-3; [Substrate]o= 4.0 x 10-3 mol dm-3;[HClO4] = 2.9 x 10-3 mol dm-3.
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