Skip to main content

Table 1 Effect of varying CAT, TCA and HClO 4 concentrations on the rate of reaction at 300 K

From: Oxidation of tricyclic antidepressant drugs with chloramine-T in acidic solutions: kinetic, mechanistic and thermodynamic studies

104[CAT]o

103[Substrate]o

103[HClO4]

104 k /(s-1)

(mol dm-3)

(mol dm-3)

(mol dm-3)

IMP

CLM

1.0

4.0

2.9

7.62

4.94

2.0

4.0

2.9

7.54

4.80

4.0

4.0

2.9

7.65

4.89

8.0

4.0

2.9

7.59

4.96

10.0

4.0

2.9

7.50

4.83

2.0

1.0

2.9

1.92

1.58

2.0

2.0

2.9

3.73

3.27

2.0

4.0

2.9

7.54

4.80

2.0

8.0

2.9

12.0

8.32

2.0

12.0

2.9

17.4

11.5

2.0

4.0

1.0

5.94

3.16

2.0

4.0

2.9

7.54

4.80

2.0

4.0

5.0

9.60

5.62

2.0

4.0

10.0

11.9

7.11

2.0

4.0

15.0

13.7

9.59