|
Graphene on Cu
|
Graphene on SiO
2
|
---|
Acquisition
|
Raman Shift
|
FWHM
|
IG/I2D
|
Raman Shift
|
FWHM
|
IG/I2D
|
---|
|
(cm-1)
|
(cm-1)
| |
(cm-1)
|
(cm-1)
| |
---|
1
|
2711.4
|
70.0
|
0.86
|
2704.0
|
40.3
|
1.01
|
2
|
2701.3
|
60.0
|
0.60
|
2702.7
|
37.7
|
0.79
|
3
|
2699.8
|
49.2
|
0.56
|
2699.0
|
43.8
|
0.80
|
4
|
2698.2
|
46.6
|
0.46
|
2701.1
|
38.7
|
0.61
|
- Comparison of the position and FWHM of 2D peaks of subsequent Raman acquisitions as extracted by a single Lorentzian fit and evolution of the IG/I2D ratio (spectra from Figure7, Figure8). Uncertainties of the order of 0.01 – 0.04% for the 2D peak Raman shifts and of 3 – 6% for 2D peak FHWMs have been estimated. Note: results concerning transferred graphene are affected by a higher uncertainty because of pronounced secondary peaks (possibly due to residual PMMA used for graphene transfer) present in the Raman spectra (see Figure7(b)), making the fit procedure less accurate.